Sharp MX-M260 MX-M260 MX-M310 Operation Manual - Page 150

Physical And Chemical Properties, Stability And Reactivity, Toxicological Information

Page 150 highlights

MATERIAL SAFETY DATA SHEET Page : 3/4 Date Issued : Jun. 1, 2009 MSDS No. F-01791 Personal Protective Equipment Respiratory Protection : Not required under intended use. Hand Protection : Not required under intended use. Eye Protection : Not required under intended use. Skin Protection : Not required under intended use. Other Protective Equipment : Use of a dust mask and goggles are recommended when handling a large quantity of toner or during long term exposure, as with any non-toxic dust. 9.PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State : Solid Form : Powder Color : Black Odor : odorless Ph : Not applicable Boiling / Melting Point : Not applicable Softening Point(°C) : 100 - 130 Flash Point(°C) : Not applicable lgnition Point(°C ) : > 350 Explosion Properties : No data Density(g/cm³) : 1.1 (bulk density : approx. 0.35) Solubility in Water : Negligible 10.STABILITY AND REACTIVITY Stability : Stable Hazardous Reactions : Dust explosion, like most finely divided organic powders. Conditions to Avoid : Electric discharge, throwing into fire. Materials to Avoid : Oxidizing Materials Hazardous Decomposition Products : CO, CO2 and NOX Further Information : None Dermal 11.TOXICOLOGICAL INFORMATION Acute Toxicity Ingestion(oral) Inhalation Eye irritation : LD50 > 2000mg/kg (Rats) [Estimated from the other product containing similar material] : LC50 > 5.0mg/L (Rats) [Estimated from the other product containing similar material] : Not an irritant (Rabbits) [Estimated from the other product containing similar material] Skin irritation : Not an irritant (Rabbits) [Estimated from the other product containing similar material] Skin sensitizer : No sensitization[Estimated from the other product containing similar material] Mutagenicity : Negative (Ames Test) [Estimated from the other product containing similar material] Carcinogenicity : In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This classification is given to chemicals for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation, where carbon black is bound in a resin matrix, demonstrated no association between toner exposure and tumor development in rats. Chronic Effect : In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m3) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle (4mg/m3) exposure group, but no pulmonary change was reported in the lowest (1mg/m3) exposure group, the most relevant level to potential human exposures. 148

  • 1
  • 2
  • 3
  • 4
  • 5
  • 6
  • 7
  • 8
  • 9
  • 10
  • 11
  • 12
  • 13
  • 14
  • 15
  • 16
  • 17
  • 18
  • 19
  • 20
  • 21
  • 22
  • 23
  • 24
  • 25
  • 26
  • 27
  • 28
  • 29
  • 30
  • 31
  • 32
  • 33
  • 34
  • 35
  • 36
  • 37
  • 38
  • 39
  • 40
  • 41
  • 42
  • 43
  • 44
  • 45
  • 46
  • 47
  • 48
  • 49
  • 50
  • 51
  • 52
  • 53
  • 54
  • 55
  • 56
  • 57
  • 58
  • 59
  • 60
  • 61
  • 62
  • 63
  • 64
  • 65
  • 66
  • 67
  • 68
  • 69
  • 70
  • 71
  • 72
  • 73
  • 74
  • 75
  • 76
  • 77
  • 78
  • 79
  • 80
  • 81
  • 82
  • 83
  • 84
  • 85
  • 86
  • 87
  • 88
  • 89
  • 90
  • 91
  • 92
  • 93
  • 94
  • 95
  • 96
  • 97
  • 98
  • 99
  • 100
  • 101
  • 102
  • 103
  • 104
  • 105
  • 106
  • 107
  • 108
  • 109
  • 110
  • 111
  • 112
  • 113
  • 114
  • 115
  • 116
  • 117
  • 118
  • 119
  • 120
  • 121
  • 122
  • 123
  • 124
  • 125
  • 126
  • 127
  • 128
  • 129
  • 130
  • 131
  • 132
  • 133
  • 134
  • 135
  • 136
  • 137
  • 138
  • 139
  • 140
  • 141
  • 142
  • 143
  • 144
  • 145
  • 146
  • 147
  • 148
  • 149
  • 150
  • 151
  • 152
  • 153
  • 154
  • 155
  • 156
  • 157
  • 158
  • 159
  • 160
  • 161
  • 162
  • 163
  • 164
  • 165
  • 166
  • 167
  • 168

148
MATERIAL
SAFETY
DATA
SHEET
Page : 3/4
Date Issued
: Jun. 1, 2009
MSDS
No.
F-01791
Personal Protective Equipment
Respiratory Protection
: Not required under intended use.
Hand Protection
: Not required under intended use.
Eye Protection
: Not required under intended use.
Skin Protection
: Not required under intended use.
Other Protective Equipment
: Use of a dust mask and goggles are recommended when handling a large
quantity of toner or during long term exposure, as with any non-toxic dust.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State : Solid
Form : Powder
Color : Black
Odor : odorless
Ph
:
Not applicable
Boiling / Melting Point
:
Not applicable
Softening Point(°C)
:
100 - 130
Flash Point(°C)
:
Not applicable
lgnition Point(°C )
:
> 350
Explosion Properties
:
No data
Density(g/cm³)
:
1.1
(bulk density : approx. 0.35)
Solubility in Water
:
Negligible
10.STABILITY AND REACTIVITY
Stability
:
Stable
Hazardous Reactions
:
Dust explosion, like most finely divided organic powders.
Conditions to Avoid
:
Electric discharge, throwing into fire.
Materials to Avoid
:
Oxidizing Materials
Hazardous Decomposition Products :
CO, CO
2
and NO
X
Further Information
:
None Dermal
11.TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion(oral)
: LD
50
> 2000mg/kg (Rats) [Estimated from the other product containing similar material]
Inhalation
: LC
50
> 5.0mg/L (Rats) [Estimated from the other product containing similar material]
Eye irritation
: Not an irritant (Rabbits) [Estimated from the other product containing similar material]
Skin irritation
: Not an irritant (Rabbits) [Estimated from the other product containing similar material]
Skin sensitizer
: No sensitization[Estimated from the other product containing similar material]
Mutagenicity
:
Negative (Ames Test) [Estimated from the other product containing similar material]
Carcinogenicity
:
In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human
carcinogen). This classification is given to chemicals for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies
performed in animal models other than rats did not show any association between carbon black
and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation, where
carbon black is bound in a resin matrix, demonstrated no association between toner exposure
and tumor development in rats.
Chronic Effect
:
In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of
lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m
3
) exposure
group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle
(4mg/m
3
) exposure group, but no pulmonary change was reported in the lowest (1mg/m
3
)
exposure group, the most relevant level to potential human exposures.